Tetrathiafulvalene with two cyclododecane rings: synthesis.
The synthesis and electrochemical properties of several organometallic tetrathiafulvalene (TTF) dimers, whose redox units are held across -Hg-, -SiMe2-, or -PPh- links, are described.
In order to obtain electroactive transition metal complexes with original structural and electronic properties, we report herein the synthesis of the TTF 2-BisIm-Py (3) that can act as an (N,N,N) pincer.The TTF based donor with monoaniline moiety, (4-(6,7-dimethyldithio-tetrathiafulvalene)-aniline) (2), has been chosen for the Schiff base condensation reaction with 2,6-diformylpyridine.
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We investigated the effect of auxin and acetylcholine on the expression of the tomato expansin gene LeEXPA2, a specific expansin gene expressed in elongating tomato hypocotyl segments. Since auxin interferes with clathrin-mediated endocytosis, in order to regulate cellular and developmental responses we produced protoplasts from tomato elongating hypocotyls and followed the endocytotic marker.
Synthesis of Highly Functionalised Tetrathiafialvalesies by Gary John Marshallsay, B.Sc. (Hons.) A thesis submitted for the degree of Doctor of Philosophy at the University of Durham April 1994 A range of functionalised symmetrical and unsymmetrical tetrathiafulvalene (TTF) derivatives containing substituted 4,5-(propylene-.